Use Hund’s rule to derive the electronic configuration of Ce3 ion and calculate its magnetic moment on the basis of ‘spin-only’ formula. - Chemistry | Shaalaa.com
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5.17: Hund's Rule and Orbital Filling Diagrams
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libretexts.org
SOLVED:(a) Show that the following formulae summarize the Hund's rules for a shell of angular momentum l containing n electrons: S=1 / 2[(2 l 1)-|2 l 1-n|] L=S[2 l 1-n] J=|2 l-n| S (b) For a given L S -multiplet, verify that (2 L 1)(2 S 1)=∑|L-S|^|L S|(2 J 1) (c) Find the ground state of (i) Eu^2 in the configuration 4 f^7 5  s^2 p^6 (ii) Dy^3 in the configuration 4 f^9 5  s^2 p^6 (iii) Tm^3 in the configuration 4 f^12 5  s^2 p^6
SOLVED:(a) Show that the following formulae summarize the Hund's ru…
Jul 29, 2021
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